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This dataset contains snapshots of carbon dioxide and methane concentrations, total air content, stable isotope measurements of carbon dioxide, as well as measurements of molecular oxygen and nitrogen and their stable isotopic signatures. Samples come from the ALHIC1901 ice core from the Allan Hills, Antarctica. Where possible, new ages have been assigned to previous measurements from the ALHIC1503 ice core. For samples containing excess CO2 from a secondary source, estimated atmospheric CO2 ranges are included. 

Hyperspectral imaging (HSI) technology has been increasingly used in Earth and planetary sciences. This imaging technique has been successfully tested on ice cores using VNIR (visible and near-infrared, 380-1000 nm) (Garzonio et al., 2018) and near-infrared (900 - 1700 nm) (McDowell et al, 2023)  line-scan cameras. Results show that  HSI data greatly expand ice core line-scan imaging capabilities, previously used with gray or RGB cameras (see summary in Dey et al., 2023). Combinations of selected HSI bands from the hyperspectral data cube improve feature detection in ice core stratigraphy, and map distribution of volcanic material, dust, air bubbles, fractures, and ice crystals in ice cores. Captured spectral information provides unique fingerprints for specific materials present in ice cores. This method helps to guide ice core sampling because it provides non-destructive, rapid visualization of microstructural properties, layering, bubble contents, increases in dust, or presence of  tephra material. Precise identification of these atmospheric components  is important for understanding past climate drivers reconstructed from ice cores. As part of the COLDEX project (Brook et al., this meeting) we adapted the SPECIM SisuSCS HSI system for ice core imaging. The ice core scanning system is housed inside the ca. -20ºC main NSF ICF freezer, and externally computer-controlled. The operator monitors scanning operations and communicates with personnel inside of the freezer via radio.  The system is equipped with a SPECIM FX10 camera that measures up to 224 bands in the VNIR range. We modified the ice core holder tray and installed a heated enclosure for the camera. The system uses SCHOTT DCR III Fiber Optic light sources with an OSL2BIR bulb from Thorlabs. IR filters are removed to extend the light spectral range beyond the 700 nm limit without heating the ice core surface during rapid (<5 minutes) scanning of an entire meter-long section. Emitted light enters ice at a 45º angle from two top and two bottom light sources. To calibrate absolute reflectance we use three Spectralon panels with 100, 50 and 20% reflectance values with every scan as well as several secondary reflective standards and USAF targets for geometric corrections. We are developing Python-based open source data processing routines and currently comparing HSI data with existing ice core physical and chemical measurements. The goal is to fully integrate the ice core HSI system with ice core processing at the NSF ICF. Dey et al., 2023. Application of Visual Stratigraphy from Line-Scan Images to Constrain Chronology and Melt Features of a Firn Core from Coastal Antarctica. Journal of Glaciology 69(273): 179–90. https://doi.org/10.1017/jog.2022.59.Garzonio et al., 2018. A Novel Hyperspectral System for High Resolution Imaging of Ice Cores: Application to Light-Absorbing Impurities and Ice Structure. Cold Regions Science and Technology 155: 47–57. https://doi.org/10.1016/j.coldregions.2018.07.005.McDowell et al., 2023. A Cold Laboratory Hyperspectral Imaging System to Map Grain Size and Ice Layer Distributions in Firn Cores. Preprint. Ice sheets/Instrumentation. https://doi.org/10.5194/egusphere-2023-2351. 

The last glacial period was punctuated by cold intervals in the North Atlantic region that culminated in extensive iceberg discharge events. These cold intervals, known as Heinrich Stadials, are associated with abrupt climate shifts worldwide. Here, we present CO₂measurements from the West Antarctic Ice Sheet Divide ice core across Heinrich Stadials 2 to 5 at decadal-scale resolution. Our results reveal multi-decadal-scale jumps in atmospheric CO₂concentrations within each Heinrich Stadial. The largest magnitude of change (14.0 ± 0.8 ppm within 55 ± 10 y) occurred during Heinrich Stadial 4. Abrupt rises in atmospheric CO₂are concurrent with jumps in atmospheric CH₄and abrupt changes in the water isotopologs in multiple Antarctic ice cores, the latter of which suggest rapid warming of both Antarctica and Southern Ocean vapor source regions. The synchroneity of these rapid shifts points to wind-driven upwelling of relatively warm, carbon-rich waters in the Southern Ocean, likely linked to a poleward intensification of the Southern Hemisphere westerly winds. Using an isotope-enabled atmospheric circulation model, we show that observed changes in Antarctic water isotopologs can be explained by abrupt and widespread Southern Ocean warming. Our work presents evidence for a multi-decadal- to century-scale response of the Southern Ocean to changes in atmospheric circulation, demonstrating the potential for dynamic changes in Southern Ocean biogeochemistry and circulation on human timescales. Furthermore, it suggests that anthropogenic CO₂uptake in the Southern Ocean may weaken with poleward strengthening westerlies today and into the future. 

This unpublished report describes field activities in the 2022-23 Antarctic field season by the I-188 group within COLDEX. The main purpose of this work was to identify the final coring site for a proposed 1250 m ice core. 

This document details the ground-penetrating radar (GPR) collection activities carried out by I. Nesbitt in the Allan Hills during the 2019-2020 field season. This document is intended as an informal catalogue of the fild work and post-processing activities performed at the Allan Hills and later at McMurdo and elsewhere. It contains preliminary post-processing and analysis only. Any interpretation made and presented in this report based on the data herein is subject to change pending further examination. GPR was used to examine sub-ice bedrock topography and the stratigraphic relationship between two shallow ice core drill sites (CMC1 and CMC2), as well as to explore potential future drill sites. In accordance with. the project's objective to drill and analyze ancient ice at relatively shallow depths, the two main features of interest in this study are 1) bedrock topographic features in which ancient ice could be trapped, and 2) englacial stratigraphic layers, especially those which may represent large age discontinuities. 

Unpublished field report describing drilling, sampling, and temperature profiles for shallow ice cores and boreholes at Allan Hills in 2022-2023 field season 

Field report for Allan Hills ice core drilling and geophysics, field season 2023-2024 

The Center for Oldest Ice Exploration (COLDEX) is a US initiative funded to search for climate records over the last 5 million years, including locating sites for an accessible continuous ice core going back 1.5 million years. As part of this effort, COLDEX has mapped the southern flank of Dome A, East Antarctica using an instrumented Basler, including dual frequency radar observations of the ice sheet and ice bed, as well as potential fields measurements (see presentation by Kerr in EGU session G4.3) across two field seasons from Amundsen-Scott South Pole Station. The aerogeophysical system included both the UTIG VHF MARFA radar system operating at 52.5-67.5 MHz, as well as a new large high resolution UHF array from CReSIS operating at 670-750 MHz operating simultaneously. A goal of this project was to obtain airborne repeat interferometry for segments of the survey, as well as directly feed ice sheet models using englacial isochrons (see Singh presentation in EGU session CR5.6). These goals lead to a survey explicitly designed around ice sheet flow lines. While prior work had sampled the region at lithospheric scales, the COLDEX survey had two components - the first was to map the region at crustal scales (line spacing of 15 km), and the second was to map subareas at ice sheet scales (line spacing of 3 km). Immediate observations include an extensive basal unit and strong discontinuity in englacial stratigraphy that runs across the survey area and appears correlated with changes in bed interface properties. The airborne campaign will be used to inform follow up ground campaigns to understand processes relevant for old ice preservation.